The Physics of glass

FEB 01, 1982

Our quest for a satisfactory conceptual model of the way crystallization is frustrated in supercooled liquids is still in its infancy, but not for want of experimental data.

DOI: 10.1063/1.2914932

James C. Phillips

Some four thousand years ago man discovered glass in the embers of a fire built somewhere in the deserts of the Near East. A few years from now ultratransparent glass fibers will be transmitting more information than copper wires. Thus glass is at once both one of the oldest and one of the newest materials known to civilization. Yet the science of glass is still in its infancy, and the most basic questions remain largely unanswered.

This article is only available in PDF format

References

1. R. J. Charles, Sci. Am., Sept. 1967, page 127.
2. H. Jones, Rep. Prog. Phys. 36, 1425 (1973), esp. pages 1454–69; https://doi.org/RPPHAG
M. Goldstein, R. Simha, Editor, The Glass Transition and the Nature of the Glassy State, Ann. New York Acad. Sci. 279 (1976); https://doi.org/ANYAA9
G. S. Cargill, P. Chaudhari, eds., Atomic Scale Structure of Amorphous Solids, North Holland, New York (1979).
3. W. H. Zachariasen, J. Chem. Phys. 3, 162 (1935); https://doi.org/JCPSA6
K. S. Evstropyev, E. A. Porai‐Koshits, J. Non‐Cryst. Sol. 11, 170 (1972).https://doi.org/JNCSBJ
4. P. Chaudhari, P. Beardmore, M. B. Bever, Phys. Chem. Glasses 7, 157 (1966); https://doi.org/PCGLA6
R. Blachnik, A. Hoppe, J. Non‐Cryst. Solids 34, 191 (1979).https://doi.org/JNCSBJ
5. J. C. Phillips, J. Non‐Cryst. Solids 34, 153 (1979).https://doi.org/JNCSBJ
6. R. Azoulay, H. Thibierge, A. Brenac, J. Non‐Cryst. Solids 18, 33 (1975).https://doi.org/JNCSBJ
7. P. M. Bridenbaugh, G. P. Espinosa, J. E. Griffiths, J. C. Phillips, J. P. Remeika, Phys. Rev. B 20, 4140 (1979).https://doi.org/PRBMDO
8. C. H. Chen, J. C. Phillips, K. C. Tai, P. M. Bridenbaugh, Sol. State Comm. 38, 657 (1981).https://doi.org/SSCOA4
9. F. C. Frank, J. H. Van der Merwe, Proc. Roy. Soc. 198, 205 (1949).
10. J. Zarzycki, R. Mezard, Phys. Chem. Glass 3, 163 (1962).https://doi.org/PCGLA6
11. H. Verweig, J. H. J. M. Buster, J. Non‐Cryst. Sol. 34, 81 (1979).https://doi.org/JNCSBJ
12. B. O. Mysen, D. Virgo, C. M. Scarfe, Amer. Mineral. 65, 690 (1980).https://doi.org/AMMIAY
13. T. Furukawa, K. E. Fox, W. B. White, J. Chem. Phys. 75, 3226 (1981).https://doi.org/JCPSA6

More about the authors

James C. Phillips, Bell Laboratories, Murray Hill, New Jersey.