The geometry of surface layers

APR 01, 1975

Various experimental techniques show that atoms adsorbed onto a crystal surface form two‐dimensional arrays with a structure that depends on their density, the temperature and the substrate.

DOI: 10.1063/1.3068919

Peder J. Estrup

If we wish to understand the properties of a solid surface, we must begin with some picture of the geometrical arrangement of atoms in the outermost layers of the solid. Such a structural model represents an essential ingredient in any microscopic description of a material.

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References

1. P. J. Estrup, E. G. McRae, Surf. Sci. 25, 1 (1971); https://doi.org/SUSCAS
M. B. Webb, M. G. Lagally, Solid State Phys. 28, 301 (1973).https://doi.org/SSPHAE
2. E. W. Müller, T. T. Tsong, Field Ion Microscopy, American Elsevier, New York, 1969.
3. R. D. Young, PHYSICS TODAY, November 1971, page 42.
4. W. R. Graham, G. Ehrlich, Surf. Sci. 45, 530 (1974).https://doi.org/SUSCAS
5. G. Ayrault, G. Ehrlich, J. Chem. Phys. 60, 281 (1974).https://doi.org/JCPSA6
6. L. H. Germer, Z. Physik 54, 408 (1929). https://doi.org/ZEPYAA
A translation is given in L. H. Germer, Bell Syst. Tech. J. 8, 591 (1929).https://doi.org/BSTJAN
7. H. E. Farnsworth, Phys. Rev. 34, 679 (1930); https://doi.org/PHRVAO
H. E. Farnsworth, 40, 684 (1932).https://doi.org/PHRVAO , Phys. Rev.
8. J. C. Tracy, J. M. Burkstrand, CRC Crit. Rev. Solid State Sci. 4, 381 (1974).https://doi.org/CCSCBX
9. J. B. Pendry, J. Phys. C4, 3095 (1971); https://doi.org/JPSOAW
D. W. Jepsen, P. M. Marcus, F. Jona, Phys. Rev. B5, 3933 (1972); https://doi.org/PLRBAQ
G. E. Laramore, C. B. Duke, Phys. Rev. B5, 267 (1972).https://doi.org/PLRBAQ
10. J. E. Demuth, T. N. Rhodin, Surf. Sci. 42, 261 (1974).https://doi.org/SUSCAS
11. J. E. Demuth, P. M. Marcus, D. W. Jepsen, Phys. Rev. B11, 1460 (1975).https://doi.org/PLRBAQ
12. J. E. Demuth, D. W. Jepsen, P. M. Marcus, Phys. Rev. Lett. 31, 540 (1973); https://doi.org/PRLTAO
J. E. Demuth, D. W. Jepsen, P. M. Marcus, 32, 1182 (1974); https://doi.org/PRLTAO , Phys. Rev. Lett.
J. E. Demuth, D. W. Jepsen, P. M. Marcus, Surf. Sci. 45, 733 (1974).https://doi.org/SUSCAS
13. A. Ignatiev, F. Jona, D. W. Jepsen, P. M. Marcus, Surf. Sci. (in press).
14. J. A. Appelbaum, D. R. Hamann, Phys. Rev. Lett. 31, 106 (1973).https://doi.org/PRLTAO
15. M. G. Lagally, J. C. Buchholz, G. C. Wang, J. Vac. Sci. Technol. 12, 213 (1975).https://doi.org/JVSTAL
16. J. W. May, Advan. Catalysis 21, 151 (1970).https://doi.org/ADCAAX
17. E. G. McRae, H. D. Hagstrum, in Treatise on Solid State Chemistry (N. B. Hannay, ed.) Plenum Press, New York, 1975, Vol. 6, Chapter II.
18. H. H. Brongersma, J. Vac. Sci. Technol. 11, 231 (1974).https://doi.org/JVSTAL
19. G. A. Somorjai, Catal. Rev. 7, 87 (1972).https://doi.org/CTRVBY
20. V. S. Sundaram, R. S. Alben, W. D. Robertson, Surf. Sci. 46, 653 (1974).https://doi.org/SUSCAS
21. J. C. Tracy, J. Chem. Phys. 56, 2736 (1972).https://doi.org/JCPSA6
22. T. N. Taylor, P. J. Estrup, J. Vac. Sci. Technol. 10, 26 (1973); https://doi.org/JVSTAL
H. H. Madden, J. Kuppers, G. Ertl, J. Chem. Phys. 58, 3401 (1973).https://doi.org/JCPSA6
23. H. Conrad, G. Ertl, J. Koch, E. E. Latta, Surf. Sci. 43, 462 (1974).https://doi.org/SUSCAS
24. D. L. Adams, L. H. Germer, Surf. Sci. 27, 21 (1971).https://doi.org/SUSCAS
25. D. L. Adams, Surface Sci. 42, 12 (1974); https://doi.org/SUSCAS
L. D. Schmidt, Catal. Rev. 9, 115 (1974).
26. P. J. Estrup, in The Structure and Chemistry of Solid Surfaces, (G. A. Somorjai, ed.), Wiley, New York, 1969.
27. C. H. Huang, PhD Thesis, Brown University (1974);
C. H. Huang, P. J. Estrup, Bull. A. P. S. 19, 357 (1974).

More about the Authors

Peder J. Estrup. Brown University, Providence, R.I..