Polymeric liquid crystals

MAY 01, 1982

Giant molecules align spontaneously to form liquid crystals that have applications in areas ranging from electronic devices to ultra‐high‐strength materials.

DOI: 10.1063/1.2915093

Edward T. Samulski

Soft contact lenses and ablative heat shields for spacecraft require materials with vastly different physical properties. Yet the materials for both—permeable elastic membranes and tenacious high‐temperature composities—are products of polymer science.

This article is only available in PDF format

References

1. A recent general review of this subject may be found in Polymer Liquid Crystals, A. Ciferri, W. R. Krigbaum, R. B. Meyer, eds., Academic, New York (1982).
2. E. T. Samulski in Liquid Crystalline Order in Polymers, A. Blumstein, ed., Academic, New York (1978);
D. B. Du Pré, E. T. Samulski, in Liquid Crystals, F. D. Saeva, ed., Marcel Dekker, New York (1979) page 203.
3. T. V. Samulski, E. T. Samulski, J. Chem. Phys. 67, 824 (1977).https://doi.org/JCPSA6
4. M. K. Grover, R. Zwanzig, Biopolymers 13, 2103 (1974).https://doi.org/BIPMAA
5. P. Pincus, P. G. de Gennes, Polym. Prepr. 18, 161 (1977);
Y. H. Kim, P. Pincus, Biopolymers 18, 2315 (1979).https://doi.org/BIPMAA
6. V. T. Rajan, C.‐W. Woo, Phys. Rev. A21, 990 (1980).https://doi.org/PLRAAN
7. L. Onsager, Ann. N.Y. Acad. Sci. 51, 627 (1949).https://doi.org/ANYAA9
8. P. J. Flory, Proc. Roy. Soc. (London) 234, 60 (1956); https://doi.org/PRLAAZ
P. J. Flory, et al., Macromolecules 11, 1119 (1978).https://doi.org/MAMOBX
9. A. Yu. Grosberg, A. R. Khokhlov, Adv. Polym. Sci. 41, 53 (1981).https://doi.org/APSIDK
10. R. F. KayserJr., H. J. Raveche, Phys. Rev. A17, 1067 (1978).https://doi.org/PLRAAN
11. P. J. Flory, G. Ronca, Mol. Cryst. Liq. Cryst. 54, 289 (1979).https://doi.org/MCLCA5
12. M. Doi, Ferroelectrics 30, 247 (1980).https://doi.org/FEROA8
13. G. Marrucci, A. Ciferri, J. Polym. Sci., Polym. Lett. Ed. 15, 643 (1977).
14. R. B. Meyer in reference 1.
15. P. G. de Gennes, Mol. Cryst. Liq. Cryst. Lett. 34, 177 (1977) and in reference 1.
16. J. R. Fernandes, D. B. Du Pré, Mol. Cryst. Liq. Cryst. Lett. 72, 67 (1981) and private communication.
17. G. Menges, G. Hahn, Modern Plastics, October 1981, page 56;
H. Mark, Macromolecules 10, 881 (1977).
18. Y. Bouligand, Solid State Physics, Supplement 14, 259 (1978).
19. A. J. Leadbetter, P. G. Wrighton, J. de Phys. 40, C3‐234 (1979).
20. L. Liebert, L. Strzelecki, D. Van Luyen, A. M. Levelut, Eur. Polym. J. 17, 71 (1981).https://doi.org/EUPJAG

More about the Authors

Edward T. Samulski. University of Connecticut, Storrs.