Discover
/
Article

Can the scales of atomic weights and nuclidic masses be unified?

JAN 01, 1959
Edward Wichers

The current discussion about a unified scale of nuclidic masses and atomic weights * grew out of a desire to correct the indefiniteness of the chemical scale of atomic weights which results from variations in the isotopic composition of natural oxygen. Oxygen, with a defined atomic weight of 16, has been the universally accepted reference element for atomic weights since early in the present century. Earlier many chemists favored a scale based on hydrogen, with a definite atomic weight of unity. The hydrogen scale originated with Dalton and doubtless enjoyed support on the basis of Prout’s hypothesis that the hydrogen atom is the structural unit in the atoms of all other elements. However, the operational advantages of oxygen in stoichiometric determinations of atomic weights offset the logical arguments for hydrogen and in time brought about the general acceptance of the oxygen scale. It was natural to assign a whole number, sixteen, to oxygen, rather than the nonintegral number representing its atomic weight on the hydrogen scale. Thus the unit of atomic weight became one‐sixteenth the weight of an atom of oxygen.

This article is only available in PDF format

References

  1. 1. A. O. Nier, Z. Elektrochem., 58, (7) 559 (1954); https://doi.org/ZEELAI
    A. O. Nier, Science, 121, 737 (1955).https://doi.org/SCIEAS

  2. 2. E. Wichers, J. Am. Chem. Soc., 76, 2033 (1954).https://doi.org/JACSAT

  3. 3. J. Mattauch, Z. Naturforsch., 13A, (7), 572 (1958).https://doi.org/ZENAAU

  4. 4. Private communication.

More about the authors

Edward Wichers, National Bureau of Standards.

Related content
/
Article
A half century after the discovery of Hawking radiation, we are still dealing with the quantum puzzle it exposed.
/
Article
Since the discovery was first reported in 1999, researchers have uncovered many aspects of the chiral-induced spin selectivity effect, but its underlying mechanisms remain unclear.
/
Article
Metrologists are using fundamental physics to define units of measure. Now NIST has developed new quantum sensors to measure and realize the pascal.
/
Article
Nanoscale, topologically protected whirlpools of spins have the potential to move from applications in spintronics into quantum science.
This Content Appeared In
pt-cover_1959_01.jpeg

Volume 12, Number 1

Get PT newsletters in your inbox

pt_newsletter_card_blue.png
PT The Week in Physics

A collection of PT's content from the previous week delivered every Monday.

pt_newsletter_card_darkblue.png
PT New Issue Alert

Be notified about the new issue with links to highlights and the full TOC.

pt_newsletter_card_pink.png
PT Webinars & White Papers

The latest webinars, white papers and other informational resources.

By signing up you agree to allow AIP to send you email newsletters. You further agree to our privacy policy and terms of service.