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Unexpected heterogeneity in a complex fluid

JUN 17, 2010

Newtonian fluids, such as water, are described by the Navier-Stokes equations. But many everyday fluids lack a similar complete description, and researchers still seek better observations and models of their flow. Yield stress fluids (YSFs), a subset of non-Newtonian fluids that includes toothpaste and mayonnaise, hold their shape under low stress but flow under high stress. Some YSFs are also thixotropic, meaning their viscosities decrease with time during continued flow. Thixotropy in a YSF can result in heterogeneous flow—confinement of the fluidlike behavior to part of the material, which flows more and more easily, while the rest remains solid—an important phenomenon to understand and control when handling YSFs industrially. Now, Sébastien Manneville , of the École Normale Supérieure de Lyon, and colleagues have unexpectedly observed similar localized flow in a nonthixotropic YSF subjected to a shear stress. The observed behavior was transient, but it lasted a surprisingly long time: more than a day in one of their trials, several hours in others. Many of the researchers’ observations, such as the power-law dependence of the transient duration on the shear rate, remain unexplained. Even so, the data indicate that nonthixotropic YSFs are more complicated than was previously assumed, and they exemplify the importance of distinguishing between transient and steady-state behavior in YSF experiments. (T. Divoux et al., Phys. Rev. Lett. 104, 208301, 2010 .)—Johanna Miller

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Johanna L. Miller, jmiller@aip.org

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