Negative ions of molecular hydrogen

Negative ions of molecular hydrogen. The long-standing puzzle of how a hydrogen molecule can hold on to an extra electron for so long has finally been experimentally resolved. The negative molecular ion H₂⁻ is the simplest of all molecular anions. It’s unstable, but the details of its unstable states have been the subject of much confusion. They matter beyond the confines of molecular theory because an H₂⁻ collision complex is thought to be relevant to the formation of the first generation of stars. A clear signal of metastable H₂⁻ with a lifetime of microseconds was found in a 2005 mass-spectrometer experiment. Theory, however, predicted that no H₂⁻ state could survive longer than femtoseconds unless the separation between the protons was much bigger than the 0.7-Å spacing of the neutral H₂ ground state. Now for the first time, the details of the metastable state have been revealed through so-called Coulomb-explosion imaging of its wavefunction by a group at the Max Planck Institute for Nuclear Physics in Heidelberg. The team accelerated an ion beam with a small H₂⁻ component to 1 MeV and then stripped off all the electrons by passing the H₂⁻ ions through an ultrathin carbon foil. The two suddenly freed protons repelled each other and were detected downstream. The observed distribution of proton-pair kinetic energies thus released was best fitted by an ionic wavefunction with a mean interproton spacing of about 3 Å and a rotational quantum number J of 27, as shown in the figure. The centrifugal barrier created by such high spin causes the large internuclear separation that accounts for the metastable state’s lifetime of almost 10 µs. (B. Jordon-Thaden et al., Phys. Rev. Lett. 107, 193003, 2011 doi:10.1103/PhysRevLett.107.193003 .) —BMS