Analyzing the energies of x‐ray and uv photoexcited electrons, of Auger electrons and of inelastically scattered electrons, among others, has provided much new and practical information about surfaces.
In the last 15 years there has been a tremendous growth in the field of surface science, all largely made possible by the development and application of various surface spectroscopies. In this article we hope to provide a picture of a few of the principal surface spectroscopic methods and how they are applied to answer important questions in surface science. In particular, we hope to provide the reader with a perspective of the unique considerations and technical problems associated with applying spectroscopic methods to surfaces. While the particular examples we discuss are the results of colleagues and coworkers at the Thomas J. Watson IBM laboratories, we believe they are representative of the types of surface studies and spectroscopies performed in the field in general.
References
1. For general information on surface science see: G. Ertl, J. Kueppers Low Energy Electrons and Surface Chemistry Verlag Chemie, Weinheim FRG (1974); M. W. Roberts, C. S. McKee, Physics of the Gas‐Surface Interface, Oxford U.P. (1978); T. N. Rhodin, G. Ertl The Nature of the Surface Chemical Bond, North Holland, New York (1979).
2. For general information on surface spectroscopy see: Electron Spectroscopy for Chemical Analysis: Topics in Current Physics, 4, H. Ibach, ed., Springer Verlag, Berlin (1977). For UPS see: F. J. Himpsel, Adv. Phys. 32, 1 (1983); https://doi.org/ADPHAH E. W. Plummer, W. Eberhardt, in Adv. Chem. Phys. 49, 533 (1982). https://doi.org/ADCPAA For XPS see: K. Siegbahn, ESCA Applied to Free Molecules Elsevier, New York (1971). For XPS and AES see: T. A. Carlson, Photoelectron and Auger Spectroscopy Plenum, New York (1975). For AES see: C. C. Chang in Characterization of Solid Surfaces, R. F. Kane, G. B. Larrabee, eds., Plenum, New York (1974). For EELS see: H. Ibach, D. L. Mills, Electron Energy Loss Spectroscopy and Surface Vibrations, Academic, New York (1982).
3. J. F. van der Veen, F. J. Himpsel, D. E. Eastman, Phys. Rev. B25, 7388 (1982); https://doi.org/PRBMDO R. A. Pollak, F. J. Himpsel, G. Hollander, to be published in Phys. Rev. B.
4. F. J. Himpsel, P. Heimann, D. E. Eastman, Phys. Rev. B24, 2003 (1981).https://doi.org/PRBMDO
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