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Article

Counting the atoms

SEP 01, 1980
Practically every element in the periodic table can be detected, down to single‐atom sensitivity, by resonance‐ionization‐spectroscopy methods involving commercially available lasers.
G. S. Hurst
M. G. Payne
S. D. Kramer
C. H. Chen

The title of this article was inspired by a similar one used by Ernest Rutherford for an unpublished lecture note now in the University of Cambridge library. Rutherford’s title was “The Counting of Atoms,” by which he could have meant the counting of individual ionized helium atoms (alpha particles), or, alternatively, he may have had in mind “decay counting” as an indirect indication that a parent atom had transmuted. With the modern pulsed laser, Rutherford’s idea becomes entirely practicable, and individual atoms can now be counted by several different methods, the subject of the present article. Our group at Oak Ridge has demonstrated these methods with apparatus like that shown in figure 1.

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References

  1. 1. For a review of the various fluorescence techniques, see W. M. Fairbank, Jr, C. Y. She, Opt. News, Spring 1979, page 4.

  2. 2. S. C. Curran, A. L. Cockroft, J. Angus, Phil. Mag. 40, 929 (1949).https://doi.org/PHMAA4

  3. 3. G. S. Hurst, M. G. Payne, S. D. Kramer, J. P. Young, Rev. Mod. Phys. 51, 767 (1979).https://doi.org/RMPHAT

  4. 4. G. S. Hurst, M. G. Payne, M. H. Nayfeh, J. P. Judish, E. B. Wagner, Phys. Rev. Lett. 35, 82 (1975).https://doi.org/PRLTAO

  5. 5. M. G. Payne, G. S. Hurst, M. H. Nayfeh, J. P. Judish, C. H. Chen, E. B. Wagner, J. P. Young, Phys. Rev. Lett. 35, 1154 (1975).https://doi.org/PRLTAO

  6. 6. G. S. Hurst, M. G. Payne, E. B. Wagner, United States Patent No. 3 987 302, “Resonance Ionization for Analytical Spectroscopy,” filed 1974 (granted 19 October, 1976).

  7. 7. G. S. Hurst, M. H. Nayfeh, J. P. Young, Appl. Phys. Lett. 30, 229 (1977).https://doi.org/APPLAB

  8. 8. G. S. Hurst, M. H. Nayfeh, J. P. Young, Phys. Rev. A, 15, 2283 (1977).

  9. 9. L. W. Grossman, G. S. Hurst, M. G. Payne, S. L. Allman, Chem. Phys. Lett. 50, 70 (1977).

  10. 10. L. W. Grossman, G. S. Hurst, S. D. Kramer, M. G. Payne, J. P. Young, Chem. Phys. Lett. 50, 207 (1977).https://doi.org/CHPLBC

  11. 11. G. S. Hurst, S. L. Allman, M. G. Payne, K. A. Marshall, K. L. SooHoo, Nucl. Instrum. Methods 155, 203 (1978).https://doi.org/NUIMAL

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  14. 14. R. Davis, Jr, J. M. Evans, in Proceedings 13th International Cosmic Radiation Conference 3, 2001 (1973).

  15. 15. J. N. Bahcall, Rev. Mod. Phys. 50, 881 (1978).

  16. 16. G. S. Hurst, S. D. Kramer, M. G. Payne, J. P. Young, IEEE Trans. Nucl. Sci. NS‐26, 133 (1979).

  17. 17. G. S. Hurst, M. G. Payne, S. D. Kramer, J. P. Young, Chem. Phys. Lett. 63, 1 (1979); https://doi.org/CHPLBC
    B. E. Lehmann, S. D. Kramer, S. L. Allman, G. S. Hurst, M. G. Payne, Chem. Phys. Lett. 71, 91 (1980).https://doi.org/CHPLBC

  18. 18. H. Chen, G. S. Hurst, M. G. Payne, “Direct counting of Xe atoms,” submitted to Chem. Phys. Lett.

  19. 19. G. S. Hurst, E. T. Arakawa, C. H. Chen, M. G. Payne, J. E. Parks, “Methods and apparatus for sorting and counting a few atoms,” submitted to the Department of Energy Patent Group.

  20. 20. H. H. Loosli, H. Oeschger, Earth and Planet. Sci. Lett. 7, 67 (1969).

  21. 21. T. Kirsten, in Origin of the Solar System (S. F. Dermott, ed.), Wiley, New York (1978); pages 267–346.

More about the authors

G. S. Hurst, Oak Ridge National Laboratory.

M. G. Payne, Oak Ridge National Laboratory.

S. D. Kramer, Oak Ridge National Laboratory.

C. H. Chen, Oak Ridge National Laboratory.

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This Content Appeared In
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Volume 33, Number 9

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