Research on their electronic states, vibrations and structural changes helps us understand these glasslike materials, which show promise in switching and amplification, as memories, and for silverless photography.
In recent years the physics of amorphous semiconductors has developed into a field so extensive and ramified that it is difficult to review in one paper. Various researchers emphasize different achievements; my choice of these is based on an attempt to give the reader an idea of the breadth of the research—from fundamental questions on electron states and atomic motions to the principles underlying some of the applications. The main difficulty with such a presentation of a more or less consistent picture is that there will necessarily be an inadequate discussion of alternative interpretations, so that the reader may get the mistaken impression that the suggested models were uniquely deduced from the experimental data. Unfortunately, crucial experiments that distinguish between different interpretations are still scarce. Nevertheless, experimental and theoretical work in the last five years have shown that some previously suggested plausible assumptions were incorrect, and the field has achieved, besides its extensive growth, significant progress in the understanding of the fundamental physics.
20. S. R. Ovshinsky, H. Fritzsche, IEEE Trans. ED‐20, 91 (1973).
21. J. Dresner, G. B. Stringfellow, J. Phys. Chem. Solids 29, 303 (1968); https://doi.org/JPCSAW K. S. Kim, D. Turnbull, J. Appl. Phys. 44, 5237 (1973) https://doi.org/JAPIAU and K. S. Kim, D. Turnbull, J. Appl. Phys. 45, 3447 (1974).https://doi.org/JAPIAU, J. Appl. Phys.
22. E. Finkman, J. Tauc, A. P. DeFonzo, in the Proceedings of the 12th International Conference on Physics of Semiconductors, (Stuttgart), Teubner (1974), page 1022.
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November 10, 2025 10:22 AM
This Content Appeared In
Volume 29, Number 10
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