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More on polaron theory history

SEP 01, 2015

DOI: 10.1063/PT.3.2897

Jozef T. Devreese

A recent Readers’ Forum section (Physics Today, April 2015, page 10 ) contains a discussion by Mark Dykman and Emmanuel Rashba about my review (October 2014, page 54 ) of Polarons by David Emin and about some aspects of the early days of polaron theory.

The term “polaron” was indeed coined by Solomon Pekar. 1 , 2 I agree that Pekar’s coinage is sometimes overlooked in the literature.

The development of the polaron concept was a gradual process initiated by Lev Landau. Pekar recognizes in his monograph 3 that “in 1933, L. D. Landau proposed an important idea on the auto-localization of an electron in an ideal crystal as a result of a lattice deformation by the field induced by the electron. These local states were assumed to be immobile, and Landau tried to associate them with F-centers in colored alkali halide crystals.” I think it is fair to state that all successive steps on polaron physics emerged from Landau’s first step.

For my book review, I found it unnecessary to write a more detailed introduction, and I limited the historical remarks on the polaron concept to the initial contributions of Landau. He introduced the nascent concept to Herbert Fröhlich, 4 who, in turn, introduced the commonly used basic polaron Hamiltonian for the continuum approximation to Jiro Yamashita, Theodore Holstein, and others, who laid the foundation of small-polaron theory.

Given the context of a short book review, I think not mentioning Pekar’s coinage of “polaron” and his important contributions does not constitute a major omission, as Dykman and Rashba suggest. In a different context—in a book or a review article—Pekar’s work would be amply cited. For example, reference contains a section devoted to Pekar’s polaron.

References

  1. 1. S. I. Pekar, J. Phys. USSR 10, 341 (1946).

  2. 2. S. I. Pekar, Zh. Eksp. Teor. Fiz. 16, 341 (1946).

  3. 3. S. I. Pekar, Issledovanija po Elektronnoj Teorii Kristallov, Gostekhizdat (1951);
    S. I. Pekar, Eng. trans., Research in Electron Theory of Crystals, AEC-tr-555, US Atomic Energy Commission (1963).

  4. 4. H. Fröhlich, Adv. Phys. 3, 325 (1954). https://doi.org/10.1080/00018735400101213

  5. 5. A. S. Alexandrov, J. T. Devreese, Advances in Polaron Physics, Springer (2010), p. 12. https://doi.org/10.1007/978-3-642-01896-1

More about the Authors

Jozef T. Devreese. (jozef.devreese@gmail.com) Antwerp, Belgium.

This Content Appeared In
pt_cover0915_cropped.jpg

Volume 68, Number 9

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